Stockton-on-Tees, a small city in northeastern England, has only one claim to fame: the first railway tracks were made and laid in the city in 1822, and the first-ever train ran on those tracks in 1825. But it might one day have another claim, also related to transportation: a locally based startup company called Air Fuel Synthesis has just produced the first gasoline from air and water.
It isn’t a lot of gas — five litres in two months — but Peter Harrison, the company’s chief executive, hopes that within two years they will build a larger plant producing a tonne a day. He envisages refinery-scale operations within 15 years.
“We’ve taken carbon dioxide from air and hydrogen from water and turned these elements into petrol,” Harrison told a conference at the Institution of Mechanical Engineers in London. Since the carbon dioxide that goes into the air when this fuel is burned exactly equals the amount that was taken out of the air when it was fabricated, it is a carbon-neutral fuel. Provided, of course, that the electricity used in the process comes from renewable sources.
No wonder that people who worry about global warming are excited about this breakthrough — but they should get excited slowly. The question was never if you could create a complex hydrocarbon like gasoline from just air and water, but how much it costs to do it, compared to just pumping oil out of the ground and refining it.
The answer in the past has been: far too much. Splitting water molecules to get hydrogen is expensive in terms of the electricity required. Carbon dioxide is easily available as the byproduct of burning coal or oil, but using that CO2 as the feedstock for artificial gasoline only postpones the moment when it gets into the atmosphere by a few days or weeks.
If you want a truly carbon-neutral fuel, then the carbon dioxide you use must come straight from the air. Prototype machines have been built (by Klaus Lackner of Columbia University and David Keith of the University of Calgary) that can extract CO2 from the air in industrial quantities, but the price per tonne at the moment is about $600.
That’s far too much, but as Lackner points out, the cost of any new technology plunges steeply once it goes into volume production. And the cost of getting hydrogen from water may also drop dramatically. Daniel Nocera of the Massachusetts Institute of Technology, has developed a catalyst made from cobalt and phosphorus that can split water at room temperature.
“I’m using cheap, Earth-abundant materials that you can mass-manufacture,” Nocera said in 2008. “As long as you can charge the surface, you can create the catalyst, and it doesn’t get any cheaper than that.” So if the hydrogen is cheap, and the cost of extracting carbon dioxide from the air also falls dramatically, how much would it cost to combine them into gas?
That’s what Air Fuel Synthesis is working on: an integrated, scalable industrial process that takes carbon dioxide from the air and hydrogen from water, combines them into methanol, and then turns that into gasoline.
Peter Harrison is cagey about his current production cost per litre: at the “proof-of-principle” stage, everything costs a fortune. But as he told The Independent in a recent interview, “You’re in a marketplace where the only way is up for the price of fossil fuel. At some point there will be a crossover where our fuel becomes cheaper.”
David Keith sees it the same way. “You’re selling this fuel, and they’re burning it, putting carbon in the air, but then you’re recapturing the same amount of carbon and selling it to them again. That’s a business model that could conceivably take a whack at the global transportation market, which is the hardest part of the climate problem to attack.”
Maybe Harrison’s process will not win the race to capture that market. Maybe the cheaper option will be to grow green algae in waste water or salt water, crush it to extract the oil from it, and then refine the oil into gasoline, diesel and so on. (Exxon-Mobil is currently spending about $100 million a year to develop that process.) But one way or another, the gas we put in our vehicles in 25 years’ time will probably not come out of the ground.
An entire industry employing millions of people, and the national budgets of entire countries, and much of the military planning by the world’s great powers, all rest on the assumption that this will never happen. Of course it will. The pressure to cut greenhouse gas emissions will grow as the temperature rises, and the desire for “energy independence” will only get stronger as oil prices rise.
Back in the 1890s, it was still unclear whether the new “horseless carriages” would ultimately be powered mainly by gas, steam or electricity. But it was already clear to those with any understanding of the interactions between markets and technology that the day of the horse-and-buggy was over, and the smart money was already getting out of buggy whips.
Gwynne Dyer is an independent journalist whose articles are published in 45 countries.


Comments: 2
Clairvoyant wrote:
That the catalyst used for splitting water may become less expensive is good: but you still cannot have more energy in the hydrogen than you put in. And the second law of thermodynamics says you cannot break even. So the conversions will be less than 100% energy efficient. So the cost of the energy in the hydrogen, and thence in the methanol, and thence in the gasoline, will be controlled by the cost of the electricity. So until you can have electricity that is "too cheap to meter" the hydrogen will not be cheap and thus neither will the methanol of gasoline.
In the same manner, Keith's recovery of carbon dioxide from the air is nonsense, until there is power that is "too cheap to meter". Extraction of carbon dioxide from air is extremely easy and extremely simple. The problem is energy cost, the energy to produce the extraction chemicals, the energy to contact the air with the extraction chemicals, and the energy to split the carbon dioxide from the extraction chemical. Can Keith bring the cost below $600 / tonne? Undoubtedly. What he cannot do is bring the energy cost down so that the carbon dioxide extracted from air is viable as a currency for energy.
Sorry but thermodynamics is a harsh task master.
on Oct 25th, 2012 at 6:04pm Report Abuse
Urban_avenger wrote:
on Oct 26th, 2012 at 12:15pm Report Abuse
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